This thread seems to have some sort of system corruption problem. the other posts can be viewed when you reply but don't show up on the main page. I copied this again.
Lost posts; glad to know I am not the only one.
Thanks RF. A basic physics review is always appreciated. I remember (now that you mention it) that emission/absorption of photons is accompanied by changes in the energy state of the electrons. I hope where you are going with this is to discuss the relationship between internal energy of the atom/molecule, and the external heat as measured by conventional (atmospheric) temperature (subject to pressure etc.) I am somewhat vague about this relationship.
Please continue.
I had to dredge your response from the reply area, so clearly they come and go.
The radiation flux for the atmosphere is described by concentric layers of a sphere. The net radiation of any given layer in equilibrium will be positive (just as you indicated might happen in your post) if that layer is receiving energy by convection and conduction and absorption of high frequency rf (sunlight) and negative if the opposite is true. In general if any given layer is cooler than the layer below it, that layer will radiate slightly more than it absorbs while any layer slightly warmer or the same will disrupt convection and conduction and therefore generally halt this effect. Now remember though that the layer emits and absorbs in both directions , but the slight net increase in emission will be up away from the surface and not back to earth.
The presence of GHG in the atmosphere does "force" the earth's temperature to a higher equilibrium value that it would otherwise have without the effect, but this is true irrespective of convective and latent heat effects. Convective and latent heat transfer has the opposite effect and dramatically cools the earth surface. The increase in radiative transfer in the upper atmosphere provides a sink for the convective and latent heat and therefore aids cooling of the surface over what would happen without consideration of this effect. Do you see why that is so?
None of this directly addresses the question of global climate change by variation of GHG concentration as far as I can see.